Electrospun nanomaterial offers great protect

Electrospinning—a cutting-edge method of manufacturing nanomaterials that takes advantage of the intriguing behavior of liquid surface tension when faced with an accumulation of electric charge—has been deployed to produce a fabric that can protect agains

Tsinghua University Press

image: A cartoon showing MXene and magnetic nanoparticles embedded in nanosheets and formed into fabric threads out of the electrospinning syringe. view more

Credit: Nano Research, Tsinghua University Press

Engineers have employed ‘electrospinning’, a new technique of manufacturing nanomaterials, to produce a novel fabric that offers high performance protection against electromagnetic interference, a phenomenon that can result in electronic device malfunction and at high levels of exposure can harm human health.

The technique is described in a paper published in Nano Research on December 31, 2022.

Electric and magnetic fields generated by electrical equipment can negatively interfere with digital systems either internally or externally. Such disruption can result in dangerous malfunctions if such devices are operating close to each other, particularly in the case of transportation or medical equipment such as pacemakers and insulin pumps. And this interference can not only affect electronic devices, but at very high levels over short periods, also human biology, which in part makes use of bioelectromagnetic processes, can be at risk.

For all these reasons, a great deal of effort goes into shielding people, devices and parts of devices from electromagnetic interference. To avoid making devices, particularly wearable ones, overly bulky and heavy, such shielding also needs to be lightweight and flexible.

Since the 1960s, such shielding has focused on the use of metal wire fabrics, metal wire blended with chemical fibers, and sliver plating. The high cost and poor flexibility was however a major barrier to widespread acceptance of such electromagnetic protective fabrics.

More recently, and largely thanks to the electromagnetic shielding needs of military stealth technologies, novel carbon-based materials from graphene to carbon aerogels and carbon nanotubes have been applied with great success in various electromagnetic absorption and shielding applications thanks to the special structures of these materials at the microscopic and nano-scale that mainly rely on scattering and reflection of radiation between layers, as well as electron transfer, to achieve high attenuation of electromagnetic waves. They also benefit from their high electrical conductivity and surface area, light weight, flexibility, and environmental sustainability.

Special mesh structure composites constructed by combining so-called one-dimensional materials (exceptionally thin ribbons or wires between 1 and 100 nanometers in length and effectively no width) and with two-dimensional materials (similarly thin materials but exiting in planar form, like an extremely thin piece of paper) have particularly excellent electromagnetic wave absorption and shielding properties.

"But even here, integrating multiple functions such as electromagnetic wave protection, durability, and comfort while maintaining the inherent flexibility of fabrics has remained a formidable challenge," said Shuo Zhang, lead author of the paper and researcher with the State Key Laboratory of Biofibers and Eco-textiles, College of Materials Science and Engineering at Qingdao University.

However, in recent years a series of two-dimensional layered structures made from carbides (any compound of carbon and a metal) and nitrides (any inorganic compound of nitrogen) have begun to attract attention amongst electromagnetic shielding researchers. These 2D materials are called ‘MXenes’ as they are produced from ‘MAX’ substances, where the M stands for an early transition metal such as titanium, vanadium and chromium; the A stands for any of the Group A elements in the periodic table such as aluminum, silicon and tin; and the X stands for carbon or nitrogen. The ‘ene’ suffix is there to suggest a nano-structural similarity to graphene.

Typically these MXenes have been produced via a process of etching them by immersing a MAX substance in hydrofluoric acid. Their 2D, layered structure offers many options for internal reflection, as well as offering superior electron transfer efficiency, high surface area, and mechanical properties, all of which deliver excellent absorption of electromagnetic waves.

The best performing MXene so far has achieved a ‘reflection loss’ performance of -41.8 decibels at 1.1 milimeters.

The researchers thought they could outdo this by exploring other methods of manufacture than etching, and looked to electrospinning. This is a technique of manufacturing extremely narrow, nano-scale fibers. A solution containing the desired material is held in a syringe tipped with a needle and then a high-voltage power source allows electric charge to gather on the surface of the liquid. At a certain point, the electrostatic repulsion between charges exceeds the surface tension of the solution. This produces an extremely fine jet of the liquid, drying as it squirts out of the syringe, and stretched out even further by electrostatic repulsion.

Electrospinning technology also offers one of the simplest and cheapest ways to prepare nanofibers, as well as being straightforward to operate.

The microstructure, diameter, orientation and stacking density of the fibers obtained by electrospinning can also be adjusted by changing the process parameters. By adding magnetic metal elements to the electrospinning precursor solution, after the electrospinning and a high-temperature thermal treatment, the resulting nanofibrous composite membranes produce significant magnetic loss that significantly enhances the electromagnetic wave attenuation performance.

The researchers electrospun a novel composite of two-dimensional MXene nanosheets combined with magnetic iron and nickel nanoparticles, as well as one-dimensional carbon nanofibers (CNFs). The multi-dimensional composite electromagnetic protective fabric obtained by electrospinning effectively avoids an agglomeration of 1D structures and a self-stacking of 2D structures—challenges that have bedevilled earlier MXene electromagnetic absorber material manufactured in the past, while slashing costs and eliminating the difficulty of processing.

Their material indeed beat the previous best performer, achieving an electromagnetic absorption performance of -54.1 decibels at 2.7 mm, while offering high flexibility and a lightweight waterproofing that offers a superior durability to the protective fabric in harsh environments.

The paper is also available on SciOpen (https://www.sciopen.com/article/10.1007/s12274-022-5368-1) by Tsinghua University Press.

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About Nano Research

Nano Research is a peer-reviewed, international and interdisciplinary research journal, publishes all aspects of nano science and technology, featured in rapid review and fast publishing, sponsored by Tsinghua University and the Chinese Chemical Society. It offers readers an attractive mix of authoritative and comprehensive reviews and original cutting-edge research papers. After 15 years of development, it has become one of the most influential academic journals in the nano field. In 2022 InCites Journal Citation Reports, Nano Research has an Impact Factor of 10.269 (9.136, 5 years), the total cites reached 29620, ranking first in China's international academic journals, and the number of highly cited papers reached 120, ranked among the top 2.8% of over 9000 academic journals.

About SciOpen

SciOpen is a professional open access resource for discovery of scientific and technical content published by the Tsinghua University Press and its publishing partners, providing the scholarly publishing community with innovative technology and market-leading capabilities. SciOpen provides end-to-end services across manuscript submission, peer review, content hosting, analytics, and identity management and expert advice to ensure each journal's development by offering a range of options across all functions as Journal Layout, Production Services, Editorial Services, Marketing and Promotions, Online Functionality, etc. By digitalizing the publishing process, SciOpen widens the reach, deepens the impact, and accelerates the exchange of ideas.

Nano Research

10.1007/s12274-022-5368-1

Electrospun Fe0.64Ni0.36/MXene/CNFs Nanofibrous Membranes with Multicomponent Heterostructures as Flexible Electromagnetic Wave Absorbers

31-Dec-2022

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